The article discusses the properties, degradation mechanisms, and storage considerations of PLA (Polylactic Acid) filament used in 3D printing. Here's a summary of key points:
Properties of PLA Filament
- Flexibility: PLA is naturally brittle but can be made more flexible through copolymerization with other materials like PCL (Poly(caprolactone)), PBAT (Poly(butylene adipate-co-butene terephthalate)), and PEG (Polyethylene glycol).
- Additives: Various additives are used to improve PLA's flexibility, including plasticizers such as lactic acid oligomers, epoxidized sunflower oil, and other vegetable oils.
Degradation Mechanisms
- Hydrolysis: The primary degradation mechanism that shortens the polymer chains over time.
- Crystallization: Occurs regardless of storage conditions. Vacuum-sealed samples show minimal degradation compared to those stored in zipper bags exposed to air.
Storage Considerations
- Vacuum Sealing: Storing PLA filament in vacuum-sealed bags significantly reduces degradation.
- Temperature and Humidity Control: Keeping the filament dry and at room temperature is crucial, but even under these conditions,
Read the full article at Hackaday
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